Hydrogen spectrum

Tap two energy levels of the hydrogen atom to make the electron jump. See the photon's energy, wavelength and colour, which series it belongs to, and where it sits in the spectrum, with the Rydberg formula filled in.

Keep it one tap away for everyday use.

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Energy levels of hydrogen

Tap a level to start the jump from, then the level to end on. Or choose them below.

The series

Try this

  • Make every jump that ends on level 2: these are the Balmer lines, and four of them are visible light (red, blue-green, blue and violet).
  • Jumps to level 1 give ultraviolet (Lyman); jumps to level 3 give infrared (Paschen). The bigger the drop, the shorter the wavelength.
  • Jump from ∞ to a level: that is the series limit, the shortest wavelength of the series.
  • Jump upwards: the atom absorbs a photon of exactly the same energy. That is why dark lines in starlight sit at the same places.
  • On the Class 12 level, see how the orbit radius grows as n² and the electron slows down as 1/n.

Check yourself

What it does

Heat hydrogen gas, or pass a spark through it, and it glows with a few sharp colours instead of a rainbow. Niels Bohr explained why: the electron in a hydrogen atom can only have certain energies, the energy levels n = 1, 2, 3 …. When it drops from a higher level to a lower one, the atom gives out one photon whose energy is exactly the difference. This page draws the levels; tap two of them to make a jump and see the photon’s energy, wavelength, frequency and colour, which series it belongs to (all jumps down to n = 1 are the Lyman series, to n = 2 Balmer, to n = 3 Paschen), and where it sits among the other lines of its series.

It follows the school topics on atoms: Class 11 Chemistry, Structure of Atom (line spectrum of hydrogen, Bohr’s model for the hydrogen atom), and Class 12 Physics, Atoms (atomic spectra, Bohr model, energy levels, the line spectra of hydrogen). Before this, try photoelectric effect lab to see light acting as photons; afterwards, spectral line identifier matches lines in real spectra and hydrogen orbital viewer shows the quantum picture of where the electron is.

How to use it

  1. Tap the level the electron starts on, then the level it ends on. Or pick them in the two boxes.
  2. A jump down gives out a photon; a jump up needs a photon of the same energy to be taken in.
  3. Read the photon’s wavelength and colour, and the working from the Rydberg formula and the energy levels.
  4. The second card shows every line of that series, crowding towards the series limit (a jump from ∞).
  5. Switch the Level to Class 12 to add the orbit radius, the electron’s speed and the energy needed to ionise the atom from the lower level.

Worked example

The page opens with a jump from n = 3 to n = 2, the red H-alpha line of the Balmer series. With R_H = 1.0968 × 10⁷ m⁻¹: 1/λ = R_H (1/2² − 1/3²) = 1,523,300 m⁻¹, so λ = 656.47 nm. The energy levels give the same answer: E₃ − E₂ = −1.511 − (−3.4) = 1.889 eV, and λ = 1,239.84 / 1.889 = 656.5 nm.

A jump from n = 4 to n = 1 is a Lyman line at 97.25 nm, deep ultraviolet. A jump from 4 to 3 is a Paschen line at 1,876 nm, infrared. On the Class 12 level, the n = 2 orbit has radius 4 × 0.0529 = 0.2117 nm, the electron moves at 1,094 km/s, and 3.4 eV removes it from the atom.

Check yourself

Five questions, fresh each time: the energy of a level, the energy of a photon from a jump, a wavelength from the Rydberg formula, the energy to ionise the atom from a level, and which level a series ends on. They use the school values 13.6 eV and R = 1.097 × 10⁷ m⁻¹. Nothing is saved.

Tips

  • Energies are negative because the electron is bound: you need to give it energy to free it. Zero is the free electron at n = ∞.
  • Only the Balmer series has visible lines: 656 nm (red), 486 nm (blue-green), 434 nm (blue) and 410 nm (violet).
  • The levels get closer together as n grows, so the lines of a series crowd together near the limit.

FAQ

Why does the page use 13.598 eV and not 13.6 eV? The nucleus moves a little as the electron goes round it. Allowing for this gives R_H, slightly smaller than R∞; the Check yourself questions use the rounded school values.

Is the Bohr model right? It gets hydrogen’s energy levels right, but electrons do not really travel in circular orbits. The quantum model replaces orbits with orbitals.

Is this from NCERT? No. It is an independent study aid that follows the same school topics, with its own pictures and numbers.

Where the numbers come from

  • Bohr model of hydrogen: Eₙ = −hcR_H/n², the Rydberg formula 1/λ = R_H(1/n₁² − 1/n₂²), series of Lyman, Balmer, Paschen, Brackett and Pfund, orbit radius n²a₀ and speed αc/n: standard physics.
  • R∞ = 10,973,731.568160 m⁻¹, proton–electron mass ratio 1,836.15267343, Bohr radius a₀ = 0.0529177210903 nm (CODATA 2018); h, e and c exact SI values. Wavelengths are vacuum values from the Bohr model (real lines are split very slightly by fine structure).
  • Checked against an independent Python calculation and the well-known values (Lyman alpha 121.57 nm, H-alpha 656.47 nm in vacuum, Balmer limit 364.7 nm).

Standard scientific values, such as constants, atomic weights and melting points, are facts found in every textbook; we name where ours were checked. If you are an author or publisher and want a value, a credit or a table changed or removed, tell us and we will act quickly.

Last updated 2026-11-09.

Change log for Hydrogen spectrum

  1. Polish pictures of #1061, #1064, #1068 and #1070 Details on GitHub
  2. Add #1068 Hydrogen spectrum and Bohr levels Details on GitHub

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